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Do you mean something like this?
The envelope here is drawn by using the upper and lower values in the data table. This is done with one Plot command, in which you have to specify the column that the fill goes between, in this case the lower.
We just added a new example file that has this graph and a couple of other examples.
Also make sure the line you want to show over is the last command in the list. Each command is drawn in order.
Does this help?